A single crystal niobium thin film was grown using molecular beam epitaxy on a c-plane sapphire wafer. Several samples were fabricated into dc resistivity test devices and coplanarwaveguide resonator chips using the same microfabrication procedures and solvent cleans. The samples were then subject to different acid cleaning treatments using different combinations of piranha, hydrofluoric acid, and buffered oxide etch solutions. The different samples expressed changes in dc resistivity in the normal and superconducting states such that the low temperature resistivities changed by more than 100\%, and the residual resistivity ratio dropped by a factor of 2. The internal quality factor of coplanar waveguide resonators measured near 5~GHz also showed significant variation at single photon powers ranging from 1.4×106 to less than 60×103. These changes correlate with the formation of surface crystallites that appear to be hydrocarbons. All observations are consistent with hydrogen diffusing into the niobium film at levels below the saturation threshold that is needed to observe niobium hydrides.
Two promising architectures for solid-state quantum information processing are electron spins in semiconductor quantum dots and the collective electromagnetic modes of superconductingcircuits. In some aspects, these two platforms are dual to one another: superconducting qubits are more easily coupled but are relatively large among quantum devices (∼mm), while electrostatically-confined electron spins are spatially compact (∼μm) but more complex to link. Here we combine beneficial aspects of both platforms in the Andreev spin qubit: the spin degree of freedom of an electronic quasiparticle trapped in the supercurrent-carrying Andreev levels of a Josephson semiconductor nanowire. We demonstrate coherent spin manipulation by combining single-shot circuit-QED readout and spin-flipping Raman transitions, finding a spin-flip time TS=17 μs and a spin coherence time T2E=52 ns. These results herald a new spin qubit with supercurrent-based circuit-QED integration and further our understanding and control of Andreev levels — the parent states of Majorana zero modes — in semiconductor-superconductor heterostructures.
Readout and control of fermionic spins in solid-state systems are key primitives of quantum information processing and microscopic magnetic sensing. The highly localized nature of mostfermionic spins decouples them from parasitic degrees of freedom, but makes long-range interoperability difficult to achieve. In light of this challenge, an active effort is underway to integrate fermionic spins with circuit quantum electrodynamics (cQED), which was originally developed in the field of superconducting qubits to achieve single-shot, quantum-non-demolition (QND) measurements and long-range couplings. However, single-shot readout of an individual spin with cQED has remained elusive due to the difficulty of coupling a resonator to a particle trapped by a charge-confining potential. Here we demonstrate the first single-shot, cQED readout of a single spin. In our novel implementation, the spin is that of an individual superconducting quasiparticle trapped in the Andreev levels of a semiconductor nanowire Josephson element. Due to a spin-orbit interaction inside the nanowire, this „superconducting spin“ directly determines the flow of supercurrent through the element. We harnessed this spin-dependent supercurrent to achieve both a zero-field spin splitting as well as a long-range interaction between the quasiparticle and a superconducting microwave resonator. Owing to the strength of this interaction in our device, measuring the resultant spin-dependent resonator frequency yielded QND spin readout with 92% fidelity in 1.9 μs and allowed us to monitor the quasiparticle’s spin in real time. These results pave the way for new „fermionic cQED“ devices: superconducting spin qubits operating at zero magnetic field, devices in which the spin has enhanced governance over the circuit, and time-domain measurements of Majorana modes.