Group-V materials such as niobium and tantalum have become popular choices for extending the performance of circuit quantum electrodynamics (cQED) platforms allowing for quantum processorsand memories with reduced error rates and more modes. The complex surface chemistry of niobium however makes identifying the main modes of decoherence difficult at millikelvin temperatures and single-photon powers. We use niobium coaxial quarter-wave cavities to study the impact of etch chemistry, prolonged atmospheric exposure, and the significance of cavity conditions prior to and during cooldown, in particular niobium hydride evolution, on single-photon coherence. We demonstrate cavities with quality factors of Qint≳1.4×109 in the single-photon regime, a 15 fold improvement over aluminum cavities of the same geometry. We rigorously quantify the sensitivity of our fabrication process to various loss mechanisms and demonstrate a 2−4× reduction in the two-level system (TLS) loss tangent and a 3−5× improvement in the residual resistivity over traditional BCP etching techniques. Finally, we demonstrate transmon integration and coherent cavity control while maintaining a cavity coherence of \SI{11.3}{ms}. The accessibility of our method, which can easily be replicated in academic-lab settings, and the demonstration of its performance mark an advancement in 3D cQED.
Current state-of-the-art superconducting microwave qubits are cooled to extremely low temperatures to avoid sources of decoherence. Higher qubit operating temperatures would significantlyincrease the cooling power available, which is desirable for scaling up the number of qubits in quantum computing architectures and integrating qubits in experiments requiring increased heat dissipation. To operate superconducting qubits at higher temperatures, it is necessary to address both quasiparticle decoherence (which becomes significant for aluminum junctions above 160 mK) and dephasing from thermal microwave photons (which are problematic above 50 mK). Using low-loss niobium trilayer junctions, which have reduced sensitivity to quasiparticles due to niobium’s higher superconducting transition temperature, we fabricate transmons with higher frequencies than previously studied, up to 24 GHz. We measure decoherence and dephasing times of about 1 us, corresponding to average qubit quality factors of approximately 105, and find that decoherence is unaffected by quasiparticles up to 1 K. Without relaxation from quasiparticles, we are able to explore dephasing from purely thermal sources, finding that our qubits can operate up to approximately 250 mK while maintaining similar performance. The thermal resilience of these qubits creates new options for scaling up quantum processors, enables hybrid quantum experiments with high heat dissipation budgets, and introduces a material platform for even higher-frequency qubits.
Niobium offers the benefit of increased operating temperatures and frequencies for Josephson junctions, which are the core component of superconducting devices. However existing niobiumprocesses are limited by more complicated fabrication methods and higher losses than now-standard aluminum junctions. Combining recent trilayer fabrication advancements, methods to remove lossy dielectrics and modern superconducting qubit design, we revisit niobium trilayer junctions and fabricate all-niobium transmons using only optical lithography. We characterize devices in the microwave domain, measuring coherence times up to 62 μs and an average qubit quality factor above 105: much closer to state-of-the-art aluminum-junction devices. We find the higher superconducting gap energy also results in reduced quasiparticle sensitivity above 0.16 K, where aluminum junction performance deteriorates. Our low-loss junction process is readily applied to standard optical-based foundry processes, opening new avenues for direct integration and scalability, and paves the way for higher-temperature and higher-frequency quantum devices.
The millimeter wave (mm-wave) frequency band provides exciting prospects for quantum science and devices, since many high-fidelity quantum emitters, including Rydberg atoms, moleculesand silicon vacancies, exhibit resonances near 100 GHz. High-Q resonators at these frequencies would give access to strong interactions between emitters and single photons, leading to rich and unexplored quantum phenomena at temperatures above 1K. We report a 3D mm-wave cavity with a measured single-photon internal quality factor of 3×107 and mode volume of 0.14×λ3 at 98.2 GHz, sufficient to reach strong coupling in a Rydberg cavity QED system. An in-situ piezo tunability of 18 MHz facilitates coupling to specific atomic transitions. Our unique, seamless and optically accessible resonator design is enabled by the realization that intersections of 3D waveguides support tightly confined bound states below the waveguide cutoff frequency. Harnessing the features of our cavity design, we realize a hybrid mm-wave and optical cavity, designed for interconversion and entanglement of mm-wave and optical photons using Rydberg atoms.
Millimeter-wave superconducting devices offer a platform for quantum experiments at temperatures above 1 K, and new avenues for studying light-matter interactions in the strong couplingregime. Using the intrinsic nonlinearity associated with kinetic inductance of thin film materials, we realize four-wave mixing at millimeter-wave frequencies, demonstrating a key component for superconducting quantum systems. We report on the performance of niobium nitride resonators around 100 GHz, patterned on thin (20-50 nm) films grown by atomic layer deposition, with sheet inductances up to 212 pH/square and critical temperatures up to 13.9 K. For films thicker than 20 nm, we measure quality factors from 1-6×104, likely limited by two-level systems. Finally we measure degenerate parametric conversion for a 95 GHz device with a forward efficiency up to +16 dB, paving the way for the development of nonlinear quantum devices at millimeter-wave frequencies.