Surface Optimization of Aluminum Resonators for Robust Quantum Device Fabrication

  1. Simon J. K. Lang,
  2. Ignaz Eisele,
  3. Alwin Maiwald,
  4. Emir Music,
  5. Luis Schwarzenbach,
  6. Carla Morán-Guizán,
  7. Johannes Weber,
  8. Daniela Zahn,
  9. Thomas Mayer,
  10. Rui N. Pereira,
  11. and Christoph Kutter
Aluminum remains the central material for superconducting qubits, and considerable effort has been devoted to optimizing its deposition and patterning for quantum devices. However,
while post-processing of Nb- and Ta-based resonators has been widely explored, primarily focusing on oxide removal using buffered oxide etch (BOE), post-treatment strategies for Al resonators remain underdeveloped. This challenge becomes particularly relevant for industry-scale fabrication with multichip bonding, where delays between sample preparation and cooldown require surface treatments that preserve low dielectric loss during extended exposure to ambient conditions. In this work, we investigate surface modification approaches for Al resonators subjected to a 24-hour delay prior to cryogenic measurement. Passivation using self-limiting oxygen and fluorine chemistries was evaluated utilizing different plasma processes. Remote oxygen plasma treatment reduced dielectric losses, in contrast to direct plasma, likely due to additional ashing of residual resist despite the formation of a thicker oxide layer on both Si and Al surfaces. A fluorine-based plasma process was developed that passivated the Al surface with fluorine for subsequent BOE treatment. However, increasing fluorine incorporation in the aluminum oxide correlated with higher loss, identifying fluorine as an unsuitable passivation material for Al resonators. Finally, selective oxide removal using HF vapor and phosphoric acid was assessed for surface preparation. HF vapor selectively etched SiO2 while preserving Al2O3, whereas phosphoric acid exhibited the opposite selectivity. Sequential application of both etches yielded dielectric losses as low as δLP=5.2×10−7 (Qi≈1.9M) in the single photon regime, demonstrating a promising pathway for robust Al-based resonator fabrication.

Development of TiN/AlN-based superconducting qubit components

  1. Benedikt Schoof,
  2. Moritz Singer,
  3. Simon Lang,
  4. Harsh Gupta,
  5. Daniela Zahn,
  6. Johannes Weber,
  7. and Marc Tornow
This paper presents the fabrication and characterization of superconducting qubit components from titanium nitride (TiN) and aluminum nitride (AlN) layers to create Josephson junctions
and superconducting resonators in an all-nitride architecture. Our methodology comprises a complete process flow for the fabrication of TiN/AlN/TiN junctions, characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), ellipsometry and DC electrical measurements. We evaluated the sputtering rates of AlN under varied conditions, the critical temperatures of TiN thin films for different sputtering environments, and the internal quality factors of TiN resonators in the few-GHz regime, fabricated from these films. Overall, this offered insights into the material properties critical to qubit performance. Measurements of the dependence of the critical current of the TiN / AlN / TiN junctions yielded values ranging from 150 μA to 2 μA, for AlN barrier thicknesses up to ca. 5 nm, respectively. Our findings demonstrate advances in the fabrication of nitride-based superconducting qubit components, which may find applications in quantum computing technologies based on novel materials.

Tantalum thin films sputtered on silicon and on different seed layers: material characterization and coplanar waveguide resonator performance

  1. Moritz Singer,
  2. Benedikt Schoof,
  3. Harsh Gupta,
  4. Daniela Zahn,
  5. Johannes Weber,
  6. and Marc Tornow
Superconducting qubits are a promising platform for large-scale quantum computing. Besides the Josephson junction, most parts of a superconducting qubit are made of planar, patterned
superconducting thin films. In the past, most qubit architectures have relied on niobium (Nb) as the material of choice for the superconducting layer. However, there is also a variety of alternative materials with potentially less losses, which may thereby result in increased qubit performance. One such material is tantalum (Ta), for which high-performance qubit components have already been demonstrated. In this study, we report the sputter-deposition of Ta thin films directly on heated and unheated silicon (Si) substrates as well as onto different, nanometer-thin seed layers from tantalum nitride (TaN), titanium nitride (TiN) or aluminum nitride (AlN) that were deposited first. The thin films are characterized in terms of surface morphology, crystal structure, phase composition, critical temperature, residual resistance ratio (RRR) and RF-performance. We obtain thin films indicative of pure alpha-Ta for high temperature (600°C) sputtering directly on silicon and for Ta deposited on TaN or TiN seed layers. Coplanar waveguide (CPW) resonator measurements show that the Ta deposited directly on the heated silicon substrate performs best with internal quality factors Qi reaching 1 x 106 in the single-photon regime, measured at T=100 mK.