Reversing Hydrogen-Related Loss in α-Ta Thin Films for Quantum Device Fabrication

  1. D. P. Lozano,
  2. M. Mongillo,
  3. B. Raes,
  4. Y. Canvel,
  5. S. Massar,
  6. A. M. Vadiraj,
  7. Ts. Ivanov,
  8. R. Acharya,
  9. J. Van Damme,
  10. J. Van de Vondel,
  11. D. Wan,
  12. A. Potocnik,
  13. and K. De Greve
α-Tantalum (α-Ta) is an emerging material for superconducting qubit fabrication due to the low microwave loss of its stable native oxide. However, hydrogen absorption during fabrication,
particularly when removing the native oxide, can degrade performance by increasing microwave loss. In this work, we demonstrate that hydrogen can enter α-Ta thin films when exposed to 10 vol% hydrofluoric acid for 3 minutes or longer, leading to an increase in power-independent ohmic loss in high-Q resonators at millikelvin temperatures. Reduced resonator performance is likely caused by the formation of non-superconducting tantalum hydride (TaHx) precipitates. We further show that annealing at 500°C in ultra-high vacuum (10−8 Torr) for one hour fully removes hydrogen and restores the resonators‘ intrinsic quality factors to ~4 million at the single-photon level. These findings identify a previously unreported loss mechanism in α-Ta and offer a pathway to reverse hydrogen-induced degradation in quantum devices based on Ta and, by extension also Nb, enabling more robust fabrication processes for superconducting qubits.

Argon milling induced decoherence mechanisms in superconducting quantum circuits

  1. J. Van Damme,
  2. Ts. Ivanov,
  3. P. Favia,
  4. T. Conard,
  5. J. Verjauw,
  6. R. Acharya,
  7. D. Perez Lozano,
  8. B. Raes,
  9. J. Van de Vondel,
  10. A. M. Vadiraj,
  11. M. Mongillo,
  12. D. Wan,
  13. J. De Boeck,
  14. A. Potočnik,
  15. and K. De Greve
The fabrication of superconducting circuits requires multiple deposition, etch and cleaning steps, each possibly introducing material property changes and microscopic defects. In this
work, we specifically investigate the process of argon milling, a potentially coherence limiting step, using niobium and aluminum superconducting resonators as a proxy for surface-limited behavior of qubits. We find that niobium microwave resonators exhibit an order of magnitude decrease in quality-factors after surface argon milling, while aluminum resonators are resilient to the same process. Extensive analysis of the niobium surface shows no change in the suboxide composition due to argon milling, while two-tone spectroscopy measurements reveal an increase in two-level system electrical dipole moments, indicating a structurally altered niobium oxide hosting larger two-level system defects. However, a short dry etch can fully recover the argon milling induced losses on niobium, offering a potential route towards state-of-the-art overlap Josephson junction qubits with niobium circuitry.