emission spectral probes (i.e., the NMR modified the atomic emission), in this paper we propose an alternative approach, i.e., by probing the scattering spectra of the quantum mechanical prober coupled to the driving microwaves, to characterize the physical features of the NMR embedded in a rf-SQUID based superconducting qubit. It is shown that, from the observed specifical frequency points in the spectra, i.e., either the dips or the peaks, the vibrational features (i.e., they are classical vibration or quantum mechanical one) and the physical parameters (typically such as the vibrational frequency and displacements) of the NMR can be determined effectively. The proposal is feasible with the current technique and should be useful to design the desired NMRs for various quantum metrological applications.